Production methods and technological progress of solid acrylic resin

Jun 28, 2025

As an important polymer material, solid acrylic resin is widely used in coatings, adhesives, plastic modification and other fields. Its production methods and technologies have been continuously optimized in recent years to meet the market demand for high-performance and environmentally friendly resins. This article will introduce the main production methods and technical characteristics of solid acrylic resin.

Solid acrylic resin is usually prepared by solution polymerization, suspension polymerization or bulk polymerization. Solution polymerization is one of the most common production processes, which is characterized by a uniform reaction system and a narrow molecular weight distribution of the product, and is suitable for the production of high-transparency and high-gloss resin products. This process usually uses organic solvents such as toluene and xylene as a medium to polymerize acrylic monomers under the action of an initiator, and finally obtains a solid resin by evaporating the solvent. However, the use of solvents may bring environmental problems, so solvent-free or low-solvent processes have received more attention in recent years.

Suspension polymerization is another important production method suitable for the production of granular solid acrylic resin. This method disperses the monomer in water, initiates the polymerization reaction through an initiator, and forms uniform particles. The advantages of suspension polymerization are simple process, low energy consumption, and easy separation and drying of the product. However, its molecular weight distribution is relatively wide, which may affect the performance of the final product.

Bulk polymerization is to polymerize acrylic monomers directly under solvent-free conditions, and the reaction rate is adjusted by controlling the temperature and the amount of initiator. The resin produced by this process has high purity and is suitable for applications that are sensitive to impurities. However, the heat dissipation problem of bulk polymerization is more prominent, and precise temperature control is required to avoid explosion.

In recent years, with the increasingly stringent environmental regulations, the production technology of solid acrylic resins is developing in the direction of greening and efficiency. For example, the use of aqueous polymerization technology can reduce the use of organic solvents, or the reaction efficiency can be improved by catalyst optimization. In addition, the research and development of functional solid acrylic resins has also become a hot topic, such as products with stronger weather resistance and chemical resistance to meet the needs of the high-end market.

In the future, with the advancement of new material technology, the production process of solid acrylic resins will be further optimized to provide better quality and environmentally friendly solutions for various industries.